Since its commercialization in the 1950s, X-ray fluorescence (XRF) spectrometry has become the dominant elemental technique of choice for determining low parts-per-million (ppm) to percentage concentration levels in solid samples, including metals, alloys, ores, rocks, soils . Since its commercialization in the 1950s, X-ray fluorescence (XRF) spectrometry has become the dominant elemental technique of choice for determining low parts-per-million (ppm) to percentage concentration levels in solid samples, including metals, alloys, ores, rocks, soils . 5. 1 X-ray fluorescence spectrometry can provide an accurate determination of metallic and many non-metallic elements in a wide variety of solid and liquid materials. This guide covers the information that should be included in an X-ray spectrometric analytical method and provides direction to the. X-ray fluorescence (XRF) is a fast, non-destructive analytical technique used to identify and quantify the elemental composition of a material. Using XRF, researchers can achieve rapid material characterization and analysis to ensure product chemistry specifications are met—and our XRF instruments provide the fast and. Some common elements are not listed in this method because they are considered "light" elements that cannot be detected by field portable x-ray fluorescence (FPXRF). These light elements are: lithium, beryllium, sodium, magnesium, aluminum, silicon, and phosphorus. Most of the analytes listed below.